The maximum clock frequency of the MSP430F5132IDAR is 25 MHz.
To use an external clock source, connect the external clock signal to the XIN pin and set the UCSSELx bits in the UCSCTL6 register to select the external clock source.
The RST/NMI pin is a dual-function pin that can be used as either a reset input (RST) or a non-maskable interrupt (NMI) input.
The built-in temperature sensor is connected to ADC channel A10. To use it, configure the ADC to read from channel A10 and then convert the resulting value to a temperature reading using the calibration data provided in the datasheet.
The maximum current that can be sourced or sunk by the GPIO pins on the MSP430F5132IDAR is 4 mA.